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(Our current efforts are focused on the following research topics)
Porphyrin-Fullerene Hybrids
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Synthesis and photophysics of porphyrin-fullerene
dyads, including both covalent and non-covalent linkages
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Studies of energy transfer and electron transfer
processes as a function of molecular topology
New Reactions for Functionalization of Fullerenes
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[2+2] Photocycloaddition of fullerenes to enones,
electron rich alkenes and alkynes
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Cycloaddition of 1,3-dipoles
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Solid state methods for high yield preparation of
functionalized fullerenes
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Methods for enantiomeric resolution of chiral
fullerene derivatives
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Nucleophilic additions to fullerenes
Spectroscopic Characterization and Electrochemical
Studies of Fullerene Adducts
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Use of MALDI mass spectrometry for following the
course of addition reactions to fullerenes
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Use of 3He NMR to determine the number
and ratio of products of addition to 3He@C60,
3He@C70 and higher fullerenes
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Use of 3He NMR to assign structures to
multiadducts of fullerenes
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Use of circular dichroism for assignment of absolute
configuration of chiral fullerenes using an empirical octant rule
Photochemical and Photophysical Studies of
Fullerenes and Reaction Intermediates
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UV-Vis and fluorescence spectra of substituted
fullerenes
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Transient absorption spectroscopy and time-resolved
fluoresence for study of kinetics of energy and electron transfer
processes
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Reactions of fullerene radical cations and formation
and reactions of fullerene triplet excited states
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Steady-state and time-resolved generation of singlet
oxygen on photoexcitation of fullerenes in aerated solutions
Bioactive Fullerene Derivatives
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Use of porphyrin-fullerene hybrids in photodynamic
therapy
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Antiviral activity of fullerene derivatives,
specifically activity of functionalized fullerenes against HIV-1 and
hepatitis-C viral strains
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Molecular modeling of interaction of fullerenes and
fullerene derivatives with HIV protease and other enzymes
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Toxicity of fullerene derivatives
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Preparation of water-soluble fullerene derivatives
Carbon Nanotubes

This site is maintained by
Alexander Volodarskiy.
Copyright ©
June, 2006
NYU Fullerene Group.
All rights reserved. Revised:
June 24, 2006.
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