(Our current efforts are focused on the following research topics)
 

Porphyrin-Fullerene Hybrids

  • Synthesis and photophysics of porphyrin-fullerene dyads, including both covalent and non-covalent linkages

  • Studies of energy transfer and electron transfer processes as a function of molecular topology
     

New Reactions for Functionalization of Fullerenes

  • [2+2] Photocycloaddition of fullerenes to enones, electron rich alkenes and alkynes

  • Cycloaddition of 1,3-dipoles

  • Solid state methods for high yield preparation of functionalized fullerenes

  • Methods for enantiomeric resolution of chiral fullerene derivatives

  • Nucleophilic additions to fullerenes

Spectroscopic Characterization and Electrochemical Studies of Fullerene Adducts

  • Use of MALDI mass spectrometry for following the course of addition reactions to fullerenes

  • Use of 3He NMR to determine the number and ratio of products of addition to 3He@C60, 3He@C70 and higher fullerenes

  • Use of 3He NMR to assign structures to multiadducts of fullerenes

  • Use of circular dichroism for assignment of absolute configuration of chiral fullerenes using an empirical octant rule
     

Photochemical and Photophysical Studies of Fullerenes and Reaction Intermediates

  • UV-Vis and fluorescence spectra of substituted fullerenes

  • Transient absorption spectroscopy and time-resolved fluoresence for study of kinetics of energy and electron transfer processes

  • Reactions of fullerene radical cations and formation and reactions of fullerene triplet excited states

  • Steady-state and time-resolved generation of singlet oxygen on photoexcitation of fullerenes in aerated solutions

Bioactive Fullerene Derivatives

  • Use of porphyrin-fullerene hybrids in photodynamic therapy

  • Antiviral activity of fullerene derivatives, specifically activity of functionalized fullerenes against HIV-1 and hepatitis-C viral strains

  • Molecular modeling of interaction of fullerenes and fullerene derivatives with HIV protease and other enzymes

  • Toxicity of fullerene derivatives

  • Preparation of water-soluble fullerene derivatives
     

Carbon Nanotubes

  • Characterization and chemical studies of single-walled carbon nanotube

  • Methods for derivitization of the tips and side wall of giant fullerenes
     

 

This site is maintained by Alexander Volodarskiy.
Copyright © June, 2006 NYU Fullerene Group.
All rights reserved. Revised: June 24, 2006.