Relation between canonical and microcanonical ensembles next up previous
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Relation between canonical and microcanonical ensembles

We saw that the E(N,V,S) and A(N,V,T) could be related by a Legendre transformation. The partition functions tex2html_wrap_inline626 and Q(N,V,T) can be related by a Laplace transform. Recall that the Laplace transform tex2html_wrap_inline666 of a function f(x) is given by

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Let us compute the Laplace transform of tex2html_wrap_inline626 with respect to E:

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Using the tex2html_wrap_inline674 -function to do the integral over E:

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By identifying tex2html_wrap_inline678 , we see that the Laplace transform of the microcanonical partition function gives the canonical partition function Q(N,V,T).



Mark Tuckerman
Sun Feb 4 23:25:26 EST 2001