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Relation to spectra

Suppose that tex2html_wrap_inline343 is a monochromatic field

displaymath98

where the parameter tex2html_wrap_inline361 insures that field goes to 0 at tex2html_wrap_inline345 . We will take tex2html_wrap_inline365 at the end of the calculation. The expectation value of B then becomes

eqnarray102

where the change of integration variables tex2html_wrap_inline369 has been made.

Define a frequency-dependent susceptibility by

displaymath111

then

displaymath117

If we let tex2html_wrap_inline371 , then we see immediately that

displaymath122

i.e., the susceptibility is just the Laplace transform of the after effect function or the time correlation function.

Recall that

displaymath128

Under time reversal, we have

eqnarray135

Thus,

displaymath154

and if A=B, then

displaymath158

Therefore

eqnarray162

From the properties of tex2html_wrap_inline375 it follows that

eqnarray179

so that tex2html_wrap_inline377 is positive for tex2html_wrap_inline379 and negative for tex2html_wrap_inline381 . It is a straightforward matter, now, to show that the energy difference tex2html_wrap_inline383 derived in the lecture from the Fermi golden rule is related to the susceptibility by

displaymath191



Mark Tuckerman
Mon Apr 28 14:54:07 EDT 2003