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Perturbative solution of the Liouville equation

As in the classical case, we assume a solution of the form

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where

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and we will assume

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Substituting into the Liouville equation and working to first order in small quantities, we find

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which is a first order inhomogeneous equation that can be solved by using an integrating factor:

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(Note that we have chosen the origin in time to be tex2html_wrap_inline345 , which is an arbitrary choice.)

For an observable A, the expectation value is

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when the solution for tex2html_wrap_inline349 is substituted in, this becomes

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where the cyclic property of the trace has been used and the Heisenberg evolution for A has been substituted in. Expanding the commutator gives

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where the cyclic property of the trace has been used again. Define a function

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called the after effect function. It is essentially the antisymmetric quantum time correlation function, which involves the commutator between A(t) and B(0). Then the linear response result can be written as

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which is the starting point for the theory of quantum transport coefficients. If we choose to measure the operator B, then we find

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Mark Tuckerman
Mon Apr 28 14:54:07 EDT 2003