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The Hamiltonian

Consider a quantum system with a Hamiltonian tex2html_wrap_inline448 . Suppose this system is subject to an external driving force tex2html_wrap_inline450 such that the full Hamiltonian takes the form

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where B is an operator through which this coupling occurs. This is the situation, for example, when the infrared spectrum is measured experimentally - the external force tex2html_wrap_inline450 is identified with an electric field E(t) and B is identified with the electric dipole moment operator. If the field tex2html_wrap_inline450 is inhomogeneous, then H takes the more general form

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where the sum is taken over Fourier modes. Often, B is an operator such that, if tex2html_wrap_inline466 , then

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Suppose we take tex2html_wrap_inline450 to be a monochromatic field of the form

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Generally, the external field can induce transitions between eigenstates of tex2html_wrap_inline448 in the system. Consider such a transition between an initial state tex2html_wrap_inline472 and a final state tex2html_wrap_inline474 , with energies tex2html_wrap_inline476 and tex2html_wrap_inline478 , respectively:

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(see figure below).

   figure66
Figure 1:

This transition can only occur if

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Mark Tuckerman
Mon Apr 28 14:50:05 EDT 2003