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Generalized equations of motion

The most general way a system can be driven away from equilibrium by a forcing function tex2html_wrap_inline709 is according to the equations of motion:

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where the 3N functions tex2html_wrap_inline713 and tex2html_wrap_inline715 are required to satisfy the incompressibility condition

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in order to insure that the Liouville equation for tex2html_wrap_inline687 is still valid. These equations of motion will give rise to a distribution function tex2html_wrap_inline687 satisfying

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with tex2html_wrap_inline695 . (We assume that f is normalized so that tex2html_wrap_inline725 .)

What does the Liouville equation say about the nature of tex2html_wrap_inline687 in the limit that tex2html_wrap_inline713 and tex2html_wrap_inline715 are small, so that the displacement away from equilibrium is, itself, small? To examine this question, we propose to solve the Liouville equation perturbatively. Thus, let us assume a solution of the form

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Note, also, that the equations of motion tex2html_wrap_inline733 take a perturbative form

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and as a result, the Liouville operator contains two pieces:

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where tex2html_wrap_inline735 and tex2html_wrap_inline737 is assumed to satisfy

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tex2html_wrap_inline739 means the Hamiltonian part of the equations of motion

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For an observable tex2html_wrap_inline741 , the ensemble average of A is a time-dependent quantity:

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which, when the assumed form for tex2html_wrap_inline687 is substituted in, gives

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where tex2html_wrap_inline747 means average with respect to tex2html_wrap_inline749 .



Mark Tuckerman
Thu Apr 13 13:07:24 EDT 2000