The most general way a system can be driven away from equilibrium by
a forcing function
is according to the equations of motion:
where the 3N functions
and
are required to satisfy the
incompressibility condition
in order to insure that the Liouville equation for
is still valid.
These equations of motion will give rise to a distribution function
satisfying
with
. (We assume that f is
normalized so that
.)
What does the Liouville equation say about the nature of
in the limit that
and
are small, so that the displacement away
from equilibrium is, itself, small? To examine this question, we propose to
solve the Liouville equation perturbatively. Thus, let us assume
a solution of the form
Note, also, that the equations of motion
take a perturbative
form
and as a result, the Liouville operator contains two pieces:
where
and
is assumed to satisfy
means the Hamiltonian part of the equations of motion
For an observable
, the ensemble average of A is a time-dependent quantity:
which, when the assumed form for
is substituted in, gives
where
means average with respect to
.