Low density, small #tex2html_wrap_inline654# limit next up previous
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Low density, small tex2html_wrap_inline628 limit

In a manner completely analogous to what was done for the fermion case, the low density limit can be treated by perturbation theory. Note that if tex2html_wrap_inline628 is not close to 1, then the divergent terms, which have a tex2html_wrap_inline658 prefactor accompanying them, will vanish in the thermodynamic limit. Thus, for the proceeding analysis, these terms can be neglected.

As before, we assume the fugacity can be expanded as

displaymath116

Then the equation for the density becomes

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By equating like powers of tex2html_wrap_inline660 on both sides, the coefficients tex2html_wrap_inline662 can be determined as they were for the fermion gas. Working to first order in tex2html_wrap_inline660 gives

displaymath123

and the equation of state is

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which is just the classical ideal gas equation. To second order, however, we find

displaymath130

and the second order equation of state becomes

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The second virial coefficient can be read off and is given by

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Interestingly, in contrast to the fermionic system, the pressure is actually decreased from its classical value as a result of bosonic spin statistics. Thus, it appears that there is an ``effective attraction'' between the particles. This fact is not entirely unexpected, given that any number of bosons can occupy the same quantum state.



Mark Tuckerman
Sat Jan 4 22:50:24 EST 2003