Consider a phase space volume element
at t=0, containing a small collection
of initial conditions on a set of trajectories. The trajectories evolve in time
according to Hamilton's equations of motion, and at a time t later
will be located in a new volume element
as shown in the figure below:
How is
related to
?
To answer this, consider a trajectory
starting from a phase space vector
in
and having a phase space vector
at time t in
. Since the solution of Hamilton's equations
depends on the choice of initial conditions,
depends on
:
Thus, the phase space vector components can be viewed as a coordinate transformation on the phase space from t=0 to time t. The phase space volume element then transforms according to
where
is the Jacobian of the transformation:
where n=6N. The precise form of the Jacobian can be determined as will be demonstrated below.
The Jacobian is the determinant of a matrix M,
whose matrix elements are
Taking the time derivative of the Jacobian, we therefore have
The matrices M
and
can be seen to be given by
Substituting into the expression for dJ/dt gives
where the chain rule has been introduced for the derivative
. The sum over i can now
be performed:
Thus,
or
The initial condition on this differential equation is
.
Moreover, for a Hamiltonian system
.
This says that dJ/dt=0 and J(0)=1. Thus,
.
If this is true, then the phase space volume element transforms according to
which is another conservation law. This conservation law states that the phase space volume occupied by a collection of systems evolving according to Hamilton's equations of motion will be preserved in time. This is one statement of Liouville's theorem.
Combining this with the fact that df/dt=0, we have a conservation law for the phase space probability:
which is an equivalent statement of Liouville's theorem.