Zero-temperature thermodynamics next up previous
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Zero-temperature thermodynamics

In order to derive an expression for the average particle number, recall that

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In the thermodynamic limit, we may take the sum over to an integration:

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But

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Therefore, it proves useful to change variables of integration from n to tex2html_wrap_inline879 , using the above relation:

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Thus,

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In order to derive an expression for the average energy, recall that the energy eigenvalues were given by

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Therefore, the average energy is given by

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At T=0, this becomes

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If the same change of variables is made, one finds that

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Thus, the average energy can be seen to be related to the average particle number by

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which is clearly not 0 (as it would be classically).

Note that the pressure can be obtained simply in the following way: Recognize that

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The energy is given by

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Thus,

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Comparing these two equations for the energy and pressure shows that

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Note, that just like the energy, the pressure at T=0 is not zero. The T=0 values of both the energy and pressure are:

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These are referred to as the zero-point energy and pressure and are purely quantum mechanical in nature. The fact that the pressure does not vanish at T=0 is again a consequence of the Pauli exclusion principle and the effective repulsive interaction that also showed up in the low density, high temperature limit. Using the expansion for tex2html_wrap_inline911 , we can derive the thermodynamics in this limit.



Mark Tuckerman
Sat Jan 4 22:04:30 EST 2003