The high density, low temperature limit next up previous
Next: Zero-temperature thermodynamics Up: No Title Previous: The high temperaturelow

The high density, low temperature limit

Recall that the density equation could be expressed as an integral

displaymath175

which lead to an expansion in powers of tex2html_wrap_inline797 . It is also possible to develop an expansion in powers of tex2html_wrap_inline829 . This is accomplished by letting

displaymath181

and developing an expansion in powers of tex2html_wrap_inline831 . In order to see how this is done, consider making a change of variables in the integral tex2html_wrap_inline833 , tex2html_wrap_inline835 , tex2html_wrap_inline837 . Then

displaymath186

Integrate by parts using

eqnarray192

so that

displaymath200

If we now expand tex2html_wrap_inline839 about tex2html_wrap_inline841 :

displaymath208

substitute this expansion into the integral and perform the resulting integrals over y, we find

displaymath216

where the fact that tex2html_wrap_inline845 has been used owing to the low temperature. Since we are in the high density limit, tex2html_wrap_inline815 is expected to be large as well so that the series, whose error goes as powers of tex2html_wrap_inline849 will converge. As tex2html_wrap_inline851 , tex2html_wrap_inline853 and only one term in the above expansion survives:

displaymath223

Solving for tex2html_wrap_inline855 gives

displaymath231

which is independent of T. The special value of the chemical potential tex2html_wrap_inline859 is known as the Fermi energy. To see what its physical meaning is, consider the expression for the average number of particles:

displaymath237

However, recall that

displaymath242

for a specific number of particles. Averaging both sides gives

displaymath246

Comparing these two expressions, we see that the average occupation number of a given state with quantum number tex2html_wrap_inline807 and m is

displaymath250

As tex2html_wrap_inline851 , tex2html_wrap_inline867 , and tex2html_wrap_inline869 if tex2html_wrap_inline871 , and tex2html_wrap_inline873 if tex2html_wrap_inline875 . Thus, at T=0, we have the result

displaymath260

A plot of the occupation average occupation number vs. tex2html_wrap_inline879 at T=0 is shown in the plot below:

   figure268
Figure 1:

Thus, at T=0, the particles will exactly fill up all of the energy levels up to an energy value tex2html_wrap_inline885 above which no energy levels will be occupied. As T is increased, the probability of an excitation above the Fermi energy becomes nonzero, and the average occupation (shown for several different values of tex2html_wrap_inline889 ) appears as follows:

  figure277
Figure 2:

Thus, there is a finite probability that some of the levels just above the Fermi energy will become occupied as T is raised slightly above T=0. At T=0, the highest occupied energy eigenvalue must satisfy

eqnarray284

This defines a spherical surface in tex2html_wrap_inline807 space, which is known as the Fermi Surface. Note that the Fermi surface is only a sphere for the ideal gas. For systems in which interactions are included, the Fermi surface can be a much more complicated surface, and studying the properties of this surface is a task that occupies the time of many a solid-state physicist.




next up previous
Next: Zero-temperature thermodynamics Up: No Title Previous: The high temperaturelow

Mark Tuckerman
Sat Jan 4 22:04:30 EST 2003