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The high temperature, low density limit

Since tex2html_wrap_inline813 , in the low density limit, the fugacity can be expanded in the form

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Writing out the first few terms in the pressure and density equations, we have

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Substituting the expansion for tex2html_wrap_inline815 into the density equation gives

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This equation can now be solved perturbatively, equating like powers of tex2html_wrap_inline799 on both sides. For example, working only to first order in tex2html_wrap_inline799 , yields:

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When this is substituted into the pressure equation, and only first order terms in the density are kept, we find

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which is just the classical ideal gas equation. Working, now, to second order in tex2html_wrap_inline799 , we have, from the density equation

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or

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Thus,

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and the equation of state becomes

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From this, we can read off the second virial coefficient

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It is particularly interesting to note that there is a nonzero second virial coefficient in spite of the fact that there are no interactions among the particles. The implication is that there is an ``effective'' interaction among the particles as a result of the fermionic spin statistics. Moreover, this effective interaction is such that is tends to increase the pressure above the classical ideal gas result ( tex2html_wrap_inline823 ). Thus, the effective interaction is repulsive in nature. This is a consequence of the Pauli exclusion principle: The particle energies must be distributed among the available levels in such a way that no two particles can occupy the same quantum state, thus giving rise to an ``effective'' repulsion between them.

If we look at the third order correction to the pressure, we find that

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so that tex2html_wrap_inline825 . Thus, one must go out to third order in the density expansion to find a contribution that tends to decrease the pressure.



Mark Tuckerman
Sat Jan 4 22:04:30 EST 2003