The harmonic oscillator - expansion about the classical path next up previous
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The harmonic oscillator - expansion about the classical path

It will be shown how to compute the density matrix for the harmonic oscillator:

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using the functional integral representation. The density matrix is given by

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As we saw in the last lecture, paths in the vicinity of the classical path on the inverted potential give rise to the dominant contribution to the functional integral. Thus, it proves useful to expand the path tex2html_wrap_inline479 about the classical path. We introduce a change of path variables from tex2html_wrap_inline479 to tex2html_wrap_inline483 , where

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where tex2html_wrap_inline485 satisfies

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subject to the conditions

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so that tex2html_wrap_inline487 .

Substituting this change of variables into the action integral yields

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An integration by parts makes the cross terms vanish:

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where the surface term vanishes becuase tex2html_wrap_inline487 and the second term vanishes because tex2html_wrap_inline491 satisfies the classical equation of motion.

The first term in the expression for S is the classical action, which we have seen is given by

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Therefore, the density matrix for the harmonic oscillator becomes

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where I[y] is the path integral

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Note that I[y] does not depend on the points x and x' and therefore can only contribute an overall (temperature dependent) constant to the density matrix. This will affect the thermodynamics but not any averages of physical observables. Nevertheless, it is important to see how such a path integral is done.

In order to compute I[y] we note that it is a functional integral over functions tex2html_wrap_inline483 that vanish at tex2html_wrap_inline507 and tex2html_wrap_inline509 . Thus, they are a special class of periodic functions and can be expanded in a Fourier sine series:

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where

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Thus, we wish to change from an integral over the functions tex2html_wrap_inline483 to an integral over the Fourier expansion coefficients tex2html_wrap_inline513 . The two integrations should be equivalent, as the coefficients uniquely determine the functions tex2html_wrap_inline483 . Note that

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Thus, terms in the action are:

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Since the cosines are orthogonal between tex2html_wrap_inline507 and tex2html_wrap_inline509 , the integral becomes

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Similarly,

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The measure becomes

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which, is not an equivalent measure (since it is not derived from a determination of the Jacobian), but is chosen to give the correct free-particle ( tex2html_wrap_inline521 ) limit, which can ultimately be corrected by attaching an overall factor of tex2html_wrap_inline523 .

With this change of variables, I[y] becomes

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The infinite product can be written as

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the product in the square brackets is just the infinite product formula for tex2html_wrap_inline527 , so that I[y] is just

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Finally, attaching the free-particle factor tex2html_wrap_inline523 , the harmonic oscillator density matrix becomes:

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Notice that in the free-particle limit tex2html_wrap_inline533 , tex2html_wrap_inline535 and tex2html_wrap_inline537 , so that

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which is the expected free-particle density matrix.


next up previous
Next: The stationary phase approximation Up: No Title Previous: No Title

Mark Tuckerman
Mon Mar 29 17:53:16 EST 1999