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Doing the path integral: the free particle

The density matrix for the free particle

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will be calculated by doing the discrete path integral explicitly and taking the limit tex2html_wrap_inline410 at the end.

The density matrix expression is

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Let us make a change of variables to

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The inverse of this transformation can be worked out explicitly, giving

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The Jacobian of the transformation is simply

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Let us see what the effect of this transformation is for the case P=3. For P=3, one must evaluate

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According to the inverse formula,

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Thus, the sum of squares becomes

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From this simple exmple, the general formula can be deduced:

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Thus, substituting this transformation into the integral gives

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where

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and the overall prefactor has been written as

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Now each of the integrals over the u variables can be integrated over independently, yielding the final result

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In order to make connection with classical statistical mechanics, we note that the prefactor is just tex2html_wrap_inline536 , where tex2html_wrap_inline538

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is the kinetic prefactor that showed up also in the classical free particle case. In terms of tex2html_wrap_inline538 , the free particle density matrix can be written as

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Thus, we see that tex2html_wrap_inline538 represents the spatial width of a free particle at finite temperature, and is called the ``thermal de Broglie wavelength.''



Mark Tuckerman
Fri Mar 10 17:55:03 EST 2000