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The canonical ensemble

In analogy to the classical canonical ensemble, the quantum canonical ensemble is defined by

eqnarray303

Thus, the quantum canonical partition function is given by

displaymath307

and the thermodynamics derived from it are the same as in the classical case:

eqnarray312

etc. Note that the expectation value of an observable A is

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Evaluating the trace in the basis of eigenvectors of H (and of tex2html_wrap_inline509 ), we obtain

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The quantum canonical ensemble will be particularly useful to us in many things to come.



Mark Tuckerman
Tue May 9 19:40:24 EDT 2000