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The microcanonical ensemble

Although we will have practically no occasion to use the quantum microcanonical ensemble (we relied on it more heavily in classical statistical mechanics), for completeness, we define it here. The function f, for this ensemble, is

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where tex2html_wrap_inline641 is the Heaviside step function. This says that tex2html_wrap_inline643 is 1 if tex2html_wrap_inline645 and 0 otherwise. The partition function for the ensemble is tex2html_wrap_inline647 , since the trace of tex2html_wrap_inline509 is the number of members in the ensemble:

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The thermodynamics that are derived from this partition function are exactly the same as they are in the classical case:

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etc.



Mark Tuckerman
Tue May 9 19:40:24 EDT 2000