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The microscopic laws of motion

Consider a system of N classical particles. The particles a confined to a particular region of space by a ``container'' of volume V. The particles have a finite kinetic energy and are therefore in constant motion, driven by the forces they exert on each other (and any external forces which may be present). At a given instant in time t, the Cartesian positions of the particles are tex2html_wrap_inline528 . The time evolution of the positions of the particles is then given by Newton's second law of motion:

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where tex2html_wrap_inline530 are the forces on each of the N particles due to all the other particles in the system. The notation tex2html_wrap_inline534 .

N

Newton's equations of motion constitute a set of 3N coupled second order differential equations. In order to solve these, it is necessary to specify a set of appropriate initial conditions on the coordinates and their first time derivaties, tex2html_wrap_inline538 . Then, the solution of Newton's equations gives the complete set of coordinates and velocities for all time t.



Mark Tuckerman
Wed Jan 8 22:51:23 EST 2003