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Experiment and theory in modern chemistry

Research in chemistry proceeds along two directions: Experimental and theoretical. Experimental chemistry is the science of observation. We pose a question to nature, carry out the corresponding experiment, and observe the outcome. What happens if we mix two substances? If we blast a molecule with a laser, what will it do? If we introduce a biomimetic into a living organism, how will it respond? Experiments produce data that relate to each individual observation. Theory, on the other hand, is concerned with building general frameworks for placing large numbers of individual observations into a rational order. It does so by building mathematical models, deducing general laws, and using these to predict the outcomes of future experiments. The tools of theory are usually mathematics and physics applied to chemical problems. Without theory, experimental science is just a vast catalog of unrationalized observations. Without experiment, theory is simply a long list of conjectures with no verification or falsification.



Keeping this juxtaposition in mind, we briefly review the basic laws of chemical transformations, keeping in mind their historical origins and the observations out of which they grew.


next up previous
Next: Fundamental laws of chemical Up: lecture_2 Previous: lecture_2
Mark E. Tuckerman 2008-09-01