The crystal field stabilization energy is defined to be the energy
difference between the actual configuration of the negatively charged
ligands and the energy of a negatively charged sphere surrounding
the metal cation. The sphere is chosen so that the
locations of the negatively charged ligands are points
of the sphere. The negatively charged sphere is called a barycenter
In the barycenter, the
orbitals are perturbed so that all of the
orbital energies are raised, but they are all perturbed in the same
way, so they are fivefold degenerate. For an octahedral arrangement,
we find that the
orbitals are
below the
energy level of the barycenter while the
orbitals
are
above the level of the barycenter.
Referring to the diagram above for the Mn
, the low-spin configuration
has a total CFSE is
, while in the high-spin
configuration, the CFSE is
.